13688-67-0

Basic information

• Product Name: 1,10-UNDECADIENE
• Synonyms: 1,10-undexadiene;undecadiene;1,10-UNDECADIENE;1,10-UNDECADIENE 90+%;Undeca-1,10-diene
• CAS NO: 13688-67-0
• Molecular Formula: C₁₁H₂₀
• Molecular Weight: 152.28
• Mol File: 13688-67-0.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 187 °C
• Flash Point: 55.7°C
• Appearance: /
• Density: 0.77
• Vapor Pressure: 1.05mmHg at 25°C
• Refractive Index: 1.4350 to 1.4380
• CAS DataBase Reference: 1,10-UNDECADIENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,10-UNDECADIENE(13688-67-0)
• EPA Substance Registry System: 1,10-UNDECADIENE(13688-67-0)

Safety Data

• RIDADR: 3295
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 13688-67-0(Hazardous Substances Data)

Usage

General Description

1,10-Undecadiene, also known as 1,10-undecadiene, is a linear alkene with the chemical formula C11H20. It is a colorless, flammable liquid that is insoluble in water but soluble in organic solvents. 1,10-Undecadiene is commonly used as a chemical intermediate in the production of polymers, plastics, and other industrial chemicals. It is also used as a monomer in the synthesis of specialty chemicals and pharmaceuticals. Due to its unsaturated structure, 1,10-Undecadiene can undergo addition reactions with various reagents to produce a wide range of derivatives with different properties and applications. Despite its utility in industry, 1,10-Undecadiene can pose health and environmental risks if handled improperly, and proper safety measures should be followed when working with this chemical.

InChI:InChI=1/C11H20/c1-3-5-7-9-11-10-8-6-4-2/h3-4H,1-2,5-11H2

Upstream product

• 106-95-6 allyl bromide 
• 23708-48-7 pentamethylenebis(magnesium bromide) 
• 1732-10-1 Dimethyl azelate 
• 111-24-0 1,5-dibromo-pentane 
• 563-47-3 3-Chloro-2-methylpropene 
• 131567-04-9 1-morpholino-1,10-undecadiene 
• 112-46-9 9-undecenol 
• 51651-40-2 nonanedial 
• 19493-09-5 Methylenetriphenylphosphorane 
• 505-52-2 brassylic acid 
• 1224431-85-9 C₁₆H₂₅NSe 
• 111-81-9 Methyl 10-undecenoate 
• 112-38-9 10-undecenoic acid 
• 112-43-6 10-Undecen-1-ol 

Downstream Products

• 123-99-9 azelaic acid 
• 36219-73-5 undec-10-en-2-one 
• 6974-31-8 11-(acetylthio)undecanoic acid 
• 71310-21-9 11-mercaptounadecanoic acid 
• 2834-05-1 11-bromoundecanoic acid 
• 1611-56-9 1-Bromo-11-hydroxyundecane 
• 765-04-8 undecane-1,11-diol 

Relevant articles and documents

Dilithium tetrachlorocuprate catalyzed coupling of allylmagnesium bromide with α,ω-dihaloalkanes

Allylmagnesium bromide has been shown to cross-couple with α,ω- dihaloalkanes in the presence of dilithium tetrachlorocuprate to yield, depending on reaction conditions, mono-coupled haloalkenes or di-coupled alkadienes. The order of the reactivity of the dihalides is I > Br >> CI and secondary halides show greater reactivity than primary halides.

Enzymatic Oxidative Tandem Decarboxylation of Dioic Acids to Terminal Dienes

The biocatalytic oxidative tandem decarboxylation of C7–C18dicarboxylic acids to terminal C5–C16dienes was catalyzed by the P450 monooxygenase OleT with conversions up to 29 % for 1,11-dodecadiene (0.49 g L–1). The sequential nature of the cascade was proven by the fact that decarboxylation of intermediate C6–C11ω-alkenoic acids and heptanedioic acid exclusively gave nonconjugated 1,4-pentadiene; scale-up allowed the isolation of 1,15-hexadecadiene and 1,11-dodecadiene; the system represents a short and green route to terminal dienes from renewable dicarboxylic acids.

Reaction of Dess-Martin periodinane with 2-(alkylselenyl)pyridines. Dehydration of primary alcohols under extraordinarily mild conditions

Dess-Martin periodinane oxidizes very rapidly 2-pyridylseleno derivatives RR′CHCH2SePy in CHCl3 or CH2Cl2 and more chemoselectively than mCPBA. Tetravalent selenanes, RR′CHCH2Se(OAc)2Py, se