136904-84-2Relevant articles and documents
Synthesis of solenopsin B via stereoselective reduction of Bicyclic N,O-ketals
Kotsuki, Hiyoshizo,Kusumi, Toshio,Inoue, Mase,Ushio, Yasuyuki,Ochi, Masamitsu
, p. 4159 - 4162 (1991)
A new enantioselective total synthesis of (-)-solenopsin B was described starting from L-glutamic acid as an optically active natural source, in which stereoselective reduction of bicyclic N,O-ketals with DIBALH was used as the key reaction step.