1369211-46-0Relevant academic research and scientific papers
Highly stable 3D homochiral coordination polymer with interweaving of double-stranded helices and extended metal-SO4-metal chains
Wu, Jie,Huang, Chao,Fu, Leixia,Wang, Pei,Song, Chuanjun,Song, Changjian,Wang, Haiyu,Hou, Hongwei,Chang, Junbiao
, p. 23 - 26 (2012)
Solvothermal synthesis of an achiral ligand N,N-bis(3-pyridyl) isophthalamide (bpip) with ZnSO4 under 120 °C yield a novel compound, [Zn(bpip)SO4]n, which displays chiral self-assembly into an infinite double-stranded helical coordination polymer consisting of two single-stranded helices with the same P handedness. These chiral infinite double-stranded helical chains are further interwoven by the 1D Zn-SO 4-Zn chains to form a novel 3D framework structure with a rare 6 5.10 topology. On the basis of the results of TG-DSC analyses, the structure is thermally stable up to ～ 467.4 °C.
