136933-88-5Relevant academic research and scientific papers
Reactions of copper(II) β-diketonates under free radical conditions. Preparation of highly congested β-diketones
Lloris, Maria E.,Galvez, Nicanor,Marquet, Jorge,Moreno-Manas, Marcial
, p. 8031 - 8042 (2007/10/02)
Copper(II) β-diketonates react with alkyl bromides under free radical conditions to give highly congested β-diketones such as 3-(1-adamantyl)-3-alkylpentane-2,4-diones. Another typical free radical reagent: benzoyl peroxide, reacts also functionalizing the intercarbonyl positions.
Alxylations of α-methyl substituted β-diketones throught their Cu(II) complexes. Preparation of sterically congested β-diketones
Lloris, Maria E.,Marquet, Jorge,Moreno-Manas, Marcial
, p. 7489 - 7492 (2007/10/02)
The copper(II) complexes of 3-methylpentane-2,4-dione and 2-methyl-1-phenylbutane-1,3-dione are good substrates for C-alkylation with several alkyl bromides including 1-bromoadamantane and 9-bromofluorene. Sterically congested β-diketones have been prepared.
