1369425-92-2Relevant academic research and scientific papers
An unexpected disproportional reaction of 2H-azirines giving (1E,3Z)-2-aza-1,3-dienes and aromatic nitriles in the presence of nickel catalysts
Okamoto, Kazuhiro,Mashida, Ayano,Watanabe, Masahito,Ohe, Kouichi
, p. 3554 - 3556 (2012/06/18)
An unprecedented nickel-catalysed disproportional reaction of 2,3-diaryl-2H-azirines forming azabutadienes and aromatic nitriles was discovered. This reaction involves the cleavage of two bonds of the 2H-azirine framework, which provides a novel type of transformation of 2H-azirines.
