136943-91-4Relevant academic research and scientific papers
Studies on sulfenamides. XIII. Reaction of 2-nitrobenzenesulfenanilides with N-bromosuccinimide
Michida,Mizuhara,Sayo
, p. 1857 - 1859 (2007/10/02)
The reaction of N-alkyl 2-nitrobenzenesulfenanilide (1a-3a) with N-bromosuccinimide (NBS) gave the corresponding monobrominated 2-nitrobenzenesulfenanilides (1b-3b) in good yields. The initial step of this reaction is the attack of NBS on the nitrogen atom of 1a-3a. The intermediate of this reaction is considered to be a cation radical of the sulfenanilides. A similar reaction of N-unsubstituted 2-nitrobenzenesulfenanilides (5a-10a) with NBS gave mono- or di-brominated 2-nitrobenzenesulfenanilides in low yields.
