1369432-39-2Relevant academic research and scientific papers
A Lewis acid-promoted reduction of acylsilanes to α-hydroxysilanes by diethylzinc
Gao, Guang,Bai, Xing-Feng,Li, Fei,Zheng, Long-Sheng,Zheng, Zhan-Jiang,Lai, Guo-Qiao,Jiang, Kezhi,Li, Fuwei,Xu, Li-Wen
supporting information; experimental part, p. 2164 - 2166 (2012/05/05)
We report here the first example of the reduction of acylsilanes to α-hydroxysilanes, in which diethylzinc was used as a highly reactive agent in the presence of Ti(OiPr)4 or other Lewis acids. The reduction typically proceeds to give synthetically useful α-hydroxysilanes in good yields.
