1369529-80-5

Basic information

• Product Name: S,S-bis(phenylMethyl)-1,2-CyclohexanediaMine
• Synonyms: S,S-bis(phenylMethyl)-1,2-CyclohexanediaMine
• CAS NO: 1369529-80-5
• Molecular Formula: C₂₀H₂₆N₂
• Molecular Weight: 294.43384
• Mol File: 1369529-80-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: S,S-bis(phenylMethyl)-1,2-CyclohexanediaMine(CAS DataBase Reference)
• NIST Chemistry Reference: S,S-bis(phenylMethyl)-1,2-CyclohexanediaMine(1369529-80-5)
• EPA Substance Registry System: S,S-bis(phenylMethyl)-1,2-CyclohexanediaMine(1369529-80-5)

Safety Data

• Hazardous Substances Data: 1369529-80-5(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 1369529-78-1 (1S,2S)-N,N-dibenzyl-N'-phthaloyl-1,2-diaminocyclohexane 

Relevant articles and documents

A new chiral primary-tertiary diamine-Bronsted acid salt organocatalyst for the highly enantioselective direct anti-aldol and syn-Mannich reactions

A new primary-tertiary diamine catalyst is easily prepared in a few steps from inexpensive, commercially available, enantiopure materials. This organocatalyst can be effective catalyzed the direct asymmetric aldol and Mannich reactions. The anti-aldol products can be obtained with up to a 99:1 anti/syn ratio and >98 % ee, while the syn-Mannich products could be obtained with up to a 99:1 syn/anti ratio and >99 % ee. Catalyst 1c can be used efficiently on a large scale with the enantioselectivities of the anti-aldol and syn-Mannich reactions being maintained at the same level, which offers a great possibility for application in industry.