136954-53-5Relevant academic research and scientific papers
The rate-limiting step in the one-electron oxidation of an alkene by oxo[meso-tetrakis(2,6-dibromophenyl)porphinato]-chromium(V) Is the formation of a charge-transfer complex
He, Gong-Xin,Arasasingham, Ramesh D.,Zhang, Guo-Hua,Bruice, Thomas C.
, p. 9828 - 9833 (2007/10/02)
We have propped, in previous studies, that the rate-limiting step in the oxidation of alkenes by hypervalent metal-oxo porphyrin spoecies is the formation of a charge-transfer (CT) complex. The CT complex then partitions, dependent upon the alkene and the
