1369968-55-7Relevant articles and documents
Micropatterning of metallopolymers: Syntheses of back-to-back coupled octylated 2,6-Bis(pyrazolyl)pyridine ligands and their solution-processable coordination polymers
Basak, Supratim,Hui, Pramiti,Boodida, Sathyanarayana,Chandrasekar, Rajadurai
, p. 3620 - 3626 (2012/06/15)
This paper presents a 10-step synthetic route for the preparation of a series of new back-to-back coupled 2,6-bis(pyrazol-1-yl)pyridine (bpp) ligands (L0-L3) decorated with tetraoctyl chains. Ligand L1 self-assembles with Zn 2+ ion to form a highly soluble metallo-supramolecular polymer 1 with Mn ~ 9600 g/mol. To demonstrate the processability of polymer 1, by following a "top-down" approach periodic one-dimensional fluorescent microstripes were fabricated on a silica substrate.