137017-02-8

Basic information

• Product Name: phenyl 2-O-(fluoren-9-yl)-1-thio-α-L-rhamnopyranoside
• CAS NO: 137017-02-8
• Molecular Weight: 420.529
• Mol File: 137017-02-8.mol

Chemical Properties

• CAS DataBase Reference: phenyl 2-O-(fluoren-9-yl)-1-thio-α-L-rhamnopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 2-O-(fluoren-9-yl)-1-thio-α-L-rhamnopyranoside(137017-02-8)
• EPA Substance Registry System: phenyl 2-O-(fluoren-9-yl)-1-thio-α-L-rhamnopyranoside(137017-02-8)

Safety Data

• Hazardous Substances Data: 137017-02-8(Hazardous Substances Data)

Upstream product

• 25023-01-2 9,9-dichloro-9H-fluorene 
• 1214-98-8 phenyl 1-thio-α-L-rhamnopyranose 
• 137016-95-6 phenyl 2,3-O-fluoren-9-ylidene-1-thio-α-L-rhamnopyranoside 

Relevant articles and documents

Preparation of dioxolane-type fluoren-9-ylidene acetals of carbohydrates and their hydrogenolysis with AlClH2 to give axial fluoren-9-yl ethers

cis-Hydroxyl groups of hexopyranosides reacted with 9,9-dichlorofluorene to give fluoren-9-ylidene acetals, hydrogenolysis of which with AlClH2 gave derivatives with axial fluoren-9-yl ether and equatorial hydroxyl groups. 1,6-Anhydro-2,3-O-fluoren-9-ylidene-β-D-mannopyranose (9) was an exception which gave a 2:3 mixture of 2-and 3-fluoren-9-yl ethers because of the marked distortion of the pyranose ring.The fluoren-9-yl ether groups could be removed easily by catalytic hydrogenation or by hydrogenolysis with the Lewis acid-type mixed hydride AlCl2H.