1370253-75-0Relevant academic research and scientific papers
The first monomeric β-diketiminate stabilized four-coordinated bismuth(III) bistrifluoromethanesulfonate
Suresh, Paladugu,Sathyanarayana, Arruri,Prabusankar, Ganesan,Hernandez, Olivier,Golhen, Stephane
, p. 617 - 620 (2012)
The sterically encumbered β-diketiminate bismuth(III) bistriflate, LBi(OSO2CF3)2 [L = HC{(CMe)N(2, 6-iPr 2C6H3)}2] (2) was prepared from a facile one-pot reaction between potassium β-diketiminate LK (1) and bismuth(III) triflate. It was characterized by elemental analysis, FT-IR, 1H NMR,13C NMR, and 19F NMR spectroscopy. The molecular structure of 2 was further confirmed by single-crystal X-ray crystallography. The solid-state structure of 2 reveals a first structurally characterized monomeric β-diketiminate supported group 15 bistriflate. The coordination number of bismuth is four. Copyright
