1370328-87-2Relevant academic research and scientific papers
Synthesis and reactivity of molybdenum and tungsten bis(dinitrogen) complexes supported by diphosphine chelates containing pendant amines
Weiss, Charles J.,Groves, Amy N.,Mock, Michael T.,Dougherty, William G.,Kassel, W. Scott,Helm, Monte L.,Dubois, Daniel L.,Bullock, R. Morris
, p. 4517 - 4529 (2012/07/03)
Molybdenum and tungsten bis(dinitrogen) complexes of the formula M(N 2)2(PNP)2 (M = Mo and W) and W(N 2)2(dppe)(PNP), supported by diphosphine ligands containing a pendant amine of the formula (CH2PR2) 2NR′ = PRNR′PR (R = Et, Ph; R′ = Me, Bn), have been prepared by Mg reduction of metal halides under an N2 atmosphere. The complexes have been characterized by NMR and IR spectroscopy, X-ray crystallography, and cyclic voltammetry. Reactivity of the target Mo and W bis(dinitrogen) compounds with CO results in the formation of dicarbonyl complexes.
