13705-07-2

Basic information

• Product Name: 2-chloro-4-(methylsulfanyl)-6-phenyl-1,3,5-triazine
• Synonyms: 1,3,5-Triazine, 2-chloro-4-methylthio-6-phenyl-; 2-CHLORO-4-METHYLTHIO-6-PHENYL-S-TRIAZINE; S-Triazine, 2-chloro-4-methylthio-6-phenyl-
• CAS NO: 13705-07-2
• Molecular Formula: C₁₀H₈ClN₃S
• Molecular Weight: 237.7086
• Mol File: 13705-07-2.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 449.5°C at 760 mmHg
• Flash Point: 225.7°C
• Density: 1.39g/cm³
• Vapor Pressure: 7.56E-08mmHg at 25°C
• Refractive Index: 1.652
• CAS DataBase Reference: 2-chloro-4-(methylsulfanyl)-6-phenyl-1,3,5-triazine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloro-4-(methylsulfanyl)-6-phenyl-1,3,5-triazine(13705-07-2)
• EPA Substance Registry System: 2-chloro-4-(methylsulfanyl)-6-phenyl-1,3,5-triazine(13705-07-2)

Safety Data

• Hazardous Substances Data: 13705-07-2(Hazardous Substances Data)

Upstream product

• 3013-02-3 S-methyl dimethylthiocarbamate 
• 17513-09-6 N′-cyanobenzamidine 
• 15760-26-6 C₃H₅N₃S 
• 611-74-5 N,N-dimethylbenzamide 
• 121032-67-5 N-carbamoyl-N'-benzoyl-S-methylisothiourea 

Downstream Products

• 1973-02-0 N²,N⁴,6-triphenyl-1,3,5-triazine-2,4-diamine 
• 34752-99-3 2-methylthio-4-phenyl-6-phenylamino-1,3,5-triazine 

Relevant articles and documents

Synthesis of 1,3,5-triazine derivatives by the reaction of S,S '-dimethyl N-cyanocarbonimidodithioate with amides

S ,S '-Dimethyl N-cyanocarbonimidodithioate (1) reacted with amides (2) in the presence of sodium hydride in a mixture of benzene and N,N-dimethylacetamide to give the corresponding N-acyl-N'-carbamoyl-S-methylisothioureas (3). Refluxing of 3 in methanol gave the corresponding cyclized product, 1,3,5-triazin-2(1H)-one derivatives (4). Compounds (4) were found to be useful intermediates for the synthesis of trisubstituted 1,3,5-triazines.

The Synthesis of Triazines from N-Cyanoamidines

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