13705-07-2

Upstream product

• 3013-02-3 S-methyl dimethylthiocarbamate 
• 17513-09-6 N′-cyanobenzamidine 
• 15760-26-6 C₃H₅N₃S 
• 611-74-5 N,N-dimethylbenzamide 
• 121032-67-5 N-carbamoyl-N'-benzoyl-S-methylisothiourea 

Downstream Products

• 34752-99-3 2-methylthio-4-phenyl-6-phenylamino-1,3,5-triazine 
• 1973-02-0 N²,N⁴,6-triphenyl-1,3,5-triazine-2,4-diamine 

Relevant academic research and scientific papers

Synthesis of 1,3,5-triazine derivatives by the reaction of S,S '-dimethyl N-cyanocarbonimidodithioate with amides

S ,S '-Dimethyl N-cyanocarbonimidodithioate (1) reacted with amides (2) in the presence of sodium hydride in a mixture of benzene and N,N-dimethylacetamide to give the corresponding N-acyl-N'-carbamoyl-S-methylisothioureas (3). Refluxing of 3 in methanol gave the corresponding cyclized product, 1,3,5-triazin-2(1H)-one derivatives (4). Compounds (4) were found to be useful intermediates for the synthesis of trisubstituted 1,3,5-triazines.