1370519-92-8Relevant academic research and scientific papers
CATALYST COMPLEXES WITH CARBENE LIGAND AND METHOD FOR MAKING SAME AND USE IN METATHESIS REACTION
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Page/Page column 30, (2014/07/23)
This invention relates to catalyst compounds and the synthesis and applications useful in olefin metathesis reactions. The catalyst compounds of the invention are represented by the formula (I): wherein M is a Group 8 metal; X1 and X2/sup
New ruthenium metathesis catalysts with chelating indenylidene ligands: Synthesis, characterization and reactivity
Kabro, Anzhelika,Ghattas, Ghazi,Roisnel, Thierry,Fischmeister, Cedric,Bruneau, Christian
supporting information; experimental part, p. 3695 - 3700 (2012/05/07)
Six new ruthenium complexes bearing a bidentate (κ2O,C)- isopropoxy-indenylidene and PPh3 or PCy3 ligands have been synthesized and characterized by 1H, 13C NMR spectroscopy and X-ray crystallography.
Cyclopropanation of strained alkenes by palladium-catalyzed reaction of 3-trimethylsilyl- or 3-pinacolatoboryl-1-arylallyl acetates
Horino, Yoshikazu,Homura, Naoki,Inoue, Kana,Yoshikawa, Saori
supporting information; experimental part, p. 828 - 834 (2012/05/04)
The palladium-catalyzed cyclopropanation of strained alkenes with 3-trimethylsilyl- or 3-pinacolatoboryl-1-arylallyl acetate derivatives is described. This reaction gives cyclopropanation products in good to high yields with a single diastereomer, and the key step is likely to involve the formation of a palladacyclobutene complex from the α-trimethylsilyl- or α-pinacolatoboryl-σ-allylpalladium complex. Copyright
