137052-25-6Relevant articles and documents
Synthesis, Properties and Use of Nitridotricarbonic Acid Tri-tert-Butyl Ester
Degerbeck, Fredrik,Grehn, Leif,Ragnarsson, Ulf
, p. 896 - 898 (2007/10/02)
Exhaustive tert-butoxycarbonylation of Boc2NH with Boc2O-DMAP furnishes Boc3N in nearly quantitative yield.This stable compound is susceptible to nucleophiles and affords Boc2NH upon aminolysis.The properties of Boc3N have been exploited in a practical one-pot procedure for the synthesis of Boc2NH from NH4Cl, which is particularly economical in the preparation of Boc215NH.