1370525-58-8

Basic information

• Product Name: [Fe2(1,3-propanedithiolate)(CO)4(cis-Ph2PCHCHPPh2)(μ-η1:η1-p-chlorophenyldiazonium)]PF6
• CAS NO: 1370525-58-8
• Molecular Weight: 1010.88
• Mol File: 1370525-58-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Fe2(1,3-propanedithiolate)(CO)4(cis-Ph2PCHCHPPh2)(μ-η1:η1-p-chlorophenyldiazonium)]PF6(CAS DataBase Reference)
• NIST Chemistry Reference: [Fe2(1,3-propanedithiolate)(CO)4(cis-Ph2PCHCHPPh2)(μ-η1:η1-p-chlorophenyldiazonium)]PF6(1370525-58-8)
• EPA Substance Registry System: [Fe2(1,3-propanedithiolate)(CO)4(cis-Ph2PCHCHPPh2)(μ-η1:η1-p-chlorophenyldiazonium)]PF6(1370525-58-8)

Safety Data

• Hazardous Substances Data: 1370525-58-8(Hazardous Substances Data)

Upstream product

• 932706-71-3 tetracarbonyl(cis-1,2-bis(diphenylphosphino)ethylene)(1,3-propanedithiolato)diiron(I) 
• 1582-27-0 4-chlorobenzene-diazonium hexafluorophosphate 

Relevant articles and documents

Reaction of aryl diazonium salts and diiron(I) dithiolato carbonyls: Evidence for radical intermediates

Treatment of Fe2(pdt)(CO)4(dppv) (1) with aryldiazonium salts affords the 34 e- adducts [Fe2(pdt) (ν-N2Ar)(CO)4(dppv)]+ (pdt2- = 1,3-propanedithiolate, dppv = cis-C2H2(PPh 2)2). Under some conditions, the same reaction gave substantial amounts of [1]+, the product of electron transfer. Consistent with the influence of electron transfer in the reactions of some electrophiles with Fe(I)Fe(I) dithiolates, the reaction of [Me3S 2]+ and Fe2(pdt)(CO)4(dppbz) was found to give [Fe2(pdt)(CO)4(dppbz)]+ as well as Me2S and Me2S2 (dppbz = 1,2- bis(diphenylphosphino)benzene).