1370636-50-2Relevant academic research and scientific papers
Dibenzophosphapentaphenes: Exploiting P chemistry for gap fine-tuning and coordination-driven assembly of planar polycyclic aromatic hydrocarbons
Bouit, Pierre-Antoine,Escande, Aude,Szuecs, Rozsa,Szieberth, Denes,Lescop, Christophe,Nyulaszi, Laszlo,Hissler, Muriel,Reau, Regis
experimental part, p. 6524 - 6527 (2012/06/15)
A synthetic route to planar P-modified polycylic aromatic hydrocarbons (PAHs) is described. The presence of a reactive σ3, λ3-P moiety within the sp2-carbon scaffold allows the preparation of a new family of PAHs displaying tunable optical and redox properties. Their frontier molecular orbitals (MOs) are derived from the corresponding phosphole MOs and show extended conjugation with the entire π framework. The coordination ability of the P center allows the coordination-driven assembly of two molecular PAHs onto a AuI ion.
