1370700-79-0Relevant academic research and scientific papers
Ruthenium(II) complexes bearing N-heterocyclic carbene ligands with wingtip groups and their catalytic activity in the transfer hydrogenation of ketones
Yi?it, Beyhan,I??k, Y?lmaz,Barut Celepci, Duygu,Evren, Enes,Yi?it, Murat,Gürbüz, Nevin,?zdemir, ?smail
, (2020)
A series of new silver(I) complexes bearing N-heterocyclic carbene (NHC) ligands with wingtip groups were synthesized by the reaction of 1,3-dialkylimidazolinium salts with silver(I) oxide in dichloromethane. The silver complexes were used as carbene-tran
Imidazolinium chloride salts bearing wingtip groups: Synthesis, molecular docking and metabolic enzymes inhibition
Yi?it, Beyhan,Kaya, Ruya,Taslimi, Parham,I??k, Y?lmaz,Karaman, Muhammet,Yi?it, Murat,?zdemir, ?smail,Gul?in, ?lhami
, p. 709 - 718 (2019/01/05)
A series of symmetrical imidazolinium chloride salts bearing secondary N-alkyl substituents were synthesized in good yield by the reaction of N,N′-dialkylethane-1,2-diamines and HC(OEt)3 in the presence of NH4Cl. These salts were characterized by spectroscopic methods. All compounds were tested as enzyme inhibitory agents. These novel symmetrical imidazolinium chloride salts derivatives (3a-h) effectively inhibited the cytosolic hCA I and hCA II, BChE, α-glycosidase and AChE with Ki values in the range of 18.41–121.73 nM for hCA I, 12.50–63.12 nM for hCA II, 3.72–34.58 nM for AChE, 5.50–32.36 nM for BChE, and 94.72–364.51 nM for α-glycosidase, respectively. CA isoenzymes play a crucial roles including acid-base balance homeostasis by excreting and secreting protons (H+) due to the CO2 hydration, HCO3 ? reabsorption mechanisms, and renal NH4 + output. Also, the molecular modeling is an implementation for estimation of the binding proximity of symmetrical imidazolinium chloride salts bearing secondary wingtip groups and their inhibition mechanisms and kinetics in atomic levels at the catalytic domains.
Rhodium(I) N-heterocyclic carbene complexes as catalysts for the hydrosilylation of aromatic ketones with triethylsilane
Yi?it, Beyhan,Yi?it, Murat,?zdemir, ?smail
, p. 75 - 79 (2017/08/04)
New rhodium(I) N-heterocyclic carbene complexes were synthesized in good yields by the reactions of rhodium dimer [Rh(OMe)COD]2 with two equivalent of 1,3-dialkylimidazolinium chloride salts in tetrahydrofuran. All of the complexes were charact
The synthesis and catalytic properties of imidazolinium salts and their palladium(II) complexes
Yigit, Beyhan
, p. 183 - 188 (2012/08/07)
Three 1,3-dialkylimidazolinium chloride salts and their palladium(II) complexes have been synthesized and characterized by elemental analysis, 1H NMR, 13C NMR and IR spectroscopy. The catalytic activities of the 1,3-dialkylimidazolinium chloride salts and their complexes in the Heck and Suzuki coupling reactions were investigated. Springer Science+Business Media B.V. 2012.
