137104-12-2Relevant academic research and scientific papers
A new synthetic route for the synthesis of enantioenriched 1,2,3,4-tetrahydronaphthalene-derived 1,3-diols
Cheng, Feng,Cai, Chen,Yang, Xing,Lin, Zi-Wei,Hu, Xiao-Song,Huang, Yi-Yong
supporting information, p. 2859 - 2865 (2018/12/04)
In this report, we presented a new approach to access a (1,3-butadiene-2-yl)carbinol, (1R,2R)- and (1S,2S)-1-(hydroxymethyl)-1-vinyl-1,2,3,4-tetrahydronaphthalene-2-ols. Starting from commercially available 1,4-diol-2-butyne, a six-step synthesis involving dibromination, Zn-mediated addition reaction of phenylpropyl aldehyde, epoxidation, epoxy–arene cyclization, and resolution with D(+)-Camphor afforded the title compounds.
Enantio- and stereocontrolled syntheses of branched-chain sugar, L-arcanose and L-olivomycose based on the chemistry of 1-trimethylsilyl-2,3-butadiene
Hatakeyama,Sugawara,Takano
, p. 4513 - 4516 (2007/10/02)
Branched-chain sugars, L-arcanose and L-olivomycose, have been synthesized in a completely enantio- and stereocontrolled manner starting from Lewis acid mediated reaction of 1-trimethylsilyl-2,3-butadiene with (S)-2-benzyloxypropanal.
