137126-07-9Relevant academic research and scientific papers
SYNTHESIS, SPECTRAL-LUMINESCENCE, AND ACID-BASE PROPERTIES OF 3-FLUORO-7-DIALKYLAMINOCOUMARINS
Gordeeva, N. A.,Kirpichenok, M. A.,Patalakha, N. S.,Khutoretskii, V. M.,Grandberg, I. I.
, p. 491 - 495 (1991)
The corresponding 3-fluoro-substituted coumarins were obtained by reactions of 7-diethylaminocoumarin, 2,3,6,7-tetrahydro-1H,5H-quinolizinocoumarin, and 2,3,6,7-tetrahydro-9-methyl-1H,5H-quinolizinocoumarin with XeF2, FClO3 or N-fluoropyridinium tetrafluoroborate.A strong mesomeric effect of the fluorine atom on the 7-amino group was established as a result of a study of the absorption and fluorescence spectra and the acid-base properties of the synthesized compounds.
