137126-24-0

Upstream product

• 94842-76-9 2,3:5,6-di-O-isopropylidene-α-D-mannofuranose 

Downstream Products

• 134472-77-8 7-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-D-glycero-D-talo-heptono-1,4-lactone 
• 132891-56-6 7-O-tert-butyldiphenylsilyl-2,3:5,6-di-O-isopropylidene-D-glycero-D-talo-heptono-1,4-lactone 
• 1567326-29-7 C₂₄H₄₀N₂O₅Si 
• 1567326-30-0 C₃₁H₄₄N₂O₆Si 
• 1567326-31-1 C₂₅H₃₀N₂O₆ 
• 1567326-32-2 C₂₅H₂₈N₂O₆ 
• 1567326-33-3 C₂₅H₂₈F₂N₂O₅ 
• 1567326-34-4 C₂₂H₂₄F₂N₂O₅ 
• 1567326-35-5 C₂₈H₃₈F₂N₂O₅Si 
• 1567326-36-6 C₃₅H₄₂F₂N₂O₆Si 
• 1567326-37-7 C₂₉H₂₈F₂N₂O₆ 
• 1567326-41-3 C₁₈H₂₅FN₂O₄ 
• 1567326-45-7 C₂₄H₄₀N₂O₅Si 
• 1567326-47-9 C₂₈H₃₈F₂N₂O₅Si 

Relevant academic research and scientific papers

APPLICATION OF THE BUCHERER REACTION TO CARBOHYDRATE DERIVATIVES

The Bucerer reaction of carbohydrate derivatives having a free carbonyl group proceeds normally, giving mainly the expected spiro-hydantoin derivatives.With derivatives having a free aldehydo group attached to an acetal ring in an α-position, the acetal ring is opened via an elimination reaction yielding unsaturated hydantoin derivatives.These reactions were studied using 1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranos-3-ulose, 2,3:4,5-di-O-isopropylidene-D-arabinose, -D-ribose, and -D-xylose, 2,3:5,6-di-O-isopropylidene-α-D-mannofuranose, 1,2-O-isopropylidene-3-O-methyl-α-D-xylo-pentodialdo-1,4-mannofuranose, 1,2:3,4-di-O-isopropylidene-α-D-galacto-hexodialdo-1,5-pyranose, and 2,3:4,5-di-O-isopropylidene-β-D-arabino-hexosulo-2,6-pyranose.