137140-13-7Relevant academic research and scientific papers
Iron-osmium bonding in clusters containing ferrocene fragments
Cullen, William R.,Rettig, Steven J.,Zheng, Tu-Cai
, p. 277 - 283 (1992)
Pyrolysis of Os3(CO)10(PFcPh2)2 and Os3(CO)11(PFc2Ph) affords Os3(CO)8(H)2[PAr(C6H 5)(η-C5H3)Fe-(η-C5H 4)] (Ar = C6H5 (3a), Fc (3b), respectively). Os3(CO)7(H)(PPri)[Fe(η-C5H 4PPri2)(η-C5H4)] (4) is a product of the thermolysis of Os3(CO)10[Fe(η-C5H4PPr i2)2]. 3b: triclinic, space group P1 (No. 2), a = 13.878 (2) A?, b = 14.145 (3) A?, c = 10.698 (2) A?, α = 104.28 (1)°, β = 110.88 (1)°, γ = 63.91 (1)°. 3a: monoclinic, space group P21/c (No. 14), a = 9.484 (3) A?, b = 18.144 (4) A?, c = 17.421 (3) A?, β = 90.10 (2)°. 4: monoclinic, space group P21/n (No. 14), a = 8.910 (3) A?, b = 22.784 (2) A?, c = 15.416 (2) A?, β = 98.25 (2)°. The complexes are electron precise if the Fe→Os bonds of length 2.830 (1) (3a), 2.826 (1) (3b), and 2.813 (1) A? (4) are included.
