137146-84-0Relevant academic research and scientific papers
A general method for the vinylation of nitrones. Synthesis of allyl hydroxylamines and allyl amines
Merino, Pedro,Anoro, Sonia,Franco, Santiago,Gascon, Jose M.,Martin, Victor,Merchan, Francisco L.,Revuelta, Julia,Tejero, Tomas,Tunon, Victoria
, p. 2989 - 3021 (2007/10/03)
An examination of the vinylation of several nitrones is presented. Whereas a complete diastereofacial discrimination was observed upon the addition of vinyl organometallic reagents to α-alkoxy nitrones, the same reaction with α-amino nitrones gave syn add
Controlled Synthesis of Regio-, Enantio-, and Diastereomers of Amino-4-pentenediols from 1,4-Pentadien-3-ol via Epoxy-4-pentenols II. erythro- and threo-3-Amino-4-pentene-1,2-diols and erythro-2-Benzylamino-4-pentene-1,3-diol
Jaeger, Volker,Stahl, Ulrich,Huemmer, Walter
, p. 776 - 782 (2007/10/02)
The regioselective reaction of amines 7 at C-3 of optically active 2,3-epoxy-4-penten-1-ol (4) and its enantiomer 5 leads to 3-amino-4-pentene-1,2-diols of both the erythro-D- and -L-series, 8, 9.The scope of this process, mediated by titanium(IV) isoprop
