137146-91-9Relevant academic research and scientific papers
Synthesis of 3,5-anhydro-2-deoxy-1,4-glyconolactones by palladium(II)-catalyzed, regioselective oxycarbonylation of C5- and C6-enitols. ω-Homologation of aldoses to produce intermediates for C-glycoside/C-nucleoside synthesis
Gracza,Hasenohrl,Stahl,Jager
, p. 1108 - 1118 (2007/10/02)
The palladium(II)-catalyzed oxycarbonylation, known with alkenols and alkenediols, is studied with optically active 4-pentenitols (-triols) 1, 7 and 5-hexenitols (-tetrols) 12, 15, 18. Efficient routes for the substrates are provided, mostly from carbohyd
Controlled Synthesis of Regio-, Enantio-, and Diastereomers of Amino-4-pentenediols from 1,4-Pentadien-3-ol via Epoxy-4-pentenols II. erythro- and threo-3-Amino-4-pentene-1,2-diols and erythro-2-Benzylamino-4-pentene-1,3-diol
Jaeger, Volker,Stahl, Ulrich,Huemmer, Walter
, p. 776 - 782 (2007/10/02)
The regioselective reaction of amines 7 at C-3 of optically active 2,3-epoxy-4-penten-1-ol (4) and its enantiomer 5 leads to 3-amino-4-pentene-1,2-diols of both the erythro-D- and -L-series, 8, 9.The scope of this process, mediated by titanium(IV) isoprop
