137156-34-4Relevant academic research and scientific papers
Study of the reactivity of nitriles towards diazomethane: synthesis and structural study of N-methyl-v-triazoles
Danoun, Saida,Baziard-Mouysset, Genevieve,Stigliani, Jean-Luc,Commenges, Gerard,Carpy, Alain,Payard, Marc
, p. 943 - 951 (2007/10/02)
In this work, we examined the effect of diazomethane on 12 nitriles.Five gave rise to three isomeric N-methyl-v-triazoles, which were isolated.Their structural features were established and, in one case, corroborated by X-ray analysis.A generalization of the structural attribution by 13C NMR is proposed.A study of the electronic distribution was carried out for a total 17 nitriles and helped establish a predictive criterion of their reactivity towards diazomethane. diazomethane / nitrile / v-triazole / electronic density
