137182-17-3Relevant academic research and scientific papers
Lithiation of (Dialkylaminomethyl)trimethylsilanes
Marumo, Kiyotaka,Inoue, Sumie,Sato, Yoshiro,Kato, Hideo
, p. 2275 - 2276 (2007/10/02)
The silylmethyl groups of (dialkylaminomethyl)trimethylsilanes 1 undergo ready lithiation with butyllithium and the resulting mixtures when quenched with chlorotrimethylsilane or aldehydes afford N,N-dialkyl(2,2,4,4-tetramethyl-2,4-disilapentyl)amines 3 or (dialkylaminomethyl)(2-hydroxyalkyl)dimethylsilanes 4.
