1372135-20-0Relevant articles and documents
Benzylic arylation of 2-methyl-5-membered heterocycles using TMP-bases
Duez, Stephanie,Steib, Andreas K.,Knochel, Paul
supporting information; experimental part, p. 1951 - 1953 (2012/06/04)
A new general Pd-catalyzed arylation of various 2-methyl-5-membered heterocycles is reported. This novel method requires Li-, Mg-, or Zn-TMP bases and allows selective metalation of the benzylic position. Subsequent Negishi cross-coupling provides the cor