1372404-62-0

Basic information

• Product Name: C₁₅H₁₂BrNO
• Synonyms: C₁₅H₁₂BrNO
• CAS NO: 1372404-62-0
• Molecular Weight: 302.17
• Mol File: 1372404-62-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₁₂BrNO(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₁₂BrNO(1372404-62-0)
• EPA Substance Registry System: C₁₅H₁₂BrNO(1372404-62-0)

Safety Data

• Hazardous Substances Data: 1372404-62-0(Hazardous Substances Data)

Upstream product

• 36132-08-8 5,7-dibromo-1H-indole 
• 13139-86-1 4-methoxyphenyl magnesium bromide 

Relevant articles and documents

Hydroxylated terphenylphosphine ligands for palladium-catalyzed ortho-selective cross-coupling of dibromophenols, dibromoanilines, and their congeners with Grignard reagents

p-Terphenylphosphines bearing one or two hydroxy groups were used as ligands to palladium in the cross-coupling of dibromophenols, dibromoanilines, and their congeners with Grignard reagents. High ortho-selectivity that cannot be achieved using other phosphine ligands was observed. ortho-Preference was also observed in competitive cross-coupling reactions of two substrates. A significant effect of the concentration of the Grignard reagent on the ortho-selectivity was observed, when the hydroxylated terphenylphosphines were used. Kinetic studies on this effect showed that high concentrations of the Grignard reagent retard the cross-coupling reaction only at the para-position, but not at the ortho-position.