137248-27-2Relevant academic research and scientific papers
Photochemical Reactions of Phenylphosphinic Azides having ortho Alkyl Substituents: Diminution of Curtius-like Rearrangement; Intramolecular Nitrene Insertion into C-H Bonds
Harger, Martin J. P.,Shimmin, P. Andrew
, p. 227 - 232 (2007/10/02)
Two types of reaction are important for the photolysis of the phosphinic azides Ar2P(O)N3 (Ar = mesityl or 2,4,6-triisopropylphenyl) in MeCN-MeOH: Curtius-like rearrangement, giving ArP(O)(OMe)NHAr, and nitrene insertion into a C-H bond of an ortho substi
