137250-33-0Relevant academic research and scientific papers
Enantio- and stereocontrolled syntheses of branched-chain sugar, L-arcanose and L-olivomycose based on the chemistry of 1-trimethylsilyl-2,3-butadiene
Hatakeyama,Sugawara,Takano
, p. 4513 - 4516 (2007/10/02)
Branched-chain sugars, L-arcanose and L-olivomycose, have been synthesized in a completely enantio- and stereocontrolled manner starting from Lewis acid mediated reaction of 1-trimethylsilyl-2,3-butadiene with (S)-2-benzyloxypropanal.
Preparation of racemic and chiral alkyl (1,3-butadien-2-yl)methanol derivatives ut,ilizing 1-trimethylsilyl-2,3-butadiene as a diene source
Hatakeyama, Susumi,Sugawara, Kazutoshi,Kawamura, Mitsuhiro,Takano, Seiichi
, p. 4509 - 4512 (2007/10/02)
Ti(IV) chloride mediated reaction of 1-trimethylsilyl-2,3-butadiene with various aldehydes and acetals has been examined establishing an efficient method for the preparation of alkyl(1,3-butadien-2-yl)methanols. Application of this method to chiral acetal
