137273-41-7

Basic information

• Product Name: 2-Cyclohexen-1-one, 2-(2-methoxyphenyl)-
• CAS NO: 137273-41-7
• Molecular Formula: C13H14O2
• Molecular Weight: 202.253
• Mol File: 137273-41-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-one, 2-(2-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one, 2-(2-methoxyphenyl)-(137273-41-7)
• EPA Substance Registry System: 2-Cyclohexen-1-one, 2-(2-methoxyphenyl)-(137273-41-7)

Safety Data

• Hazardous Substances Data: 137273-41-7(Hazardous Substances Data)

Upstream product

• 854913-24-9 2-(2-methoxy-phenyl)-cyclohex-2-enol 
• 578-57-4 2-bromoanisole 
• 77326-17-1 Trimethyl-(7-oxa-bicyclo[4.1.0]hept-2-en-2-yloxy)-silane 
• 6705-49-3 7-oxabicyclo[4.1.0]heptan-2-one 
• 31600-86-9 2-methoxyphenyllithium 
• 33948-36-6 2-iodocyclohex-2-en-1-one 
• 5720-06-9 2-Methoxyphenylboronic acid 
• 22618-48-0 1-(cyclohexen-1-yl)-2-methoxybenzene 
• 86487-17-4 2-tri-n-butylstannylanisole 
• 122948-46-3 6-oxocyclohex-1-en-1-yl trifluoromethanesulfonate 

Downstream Products

• 195001-49-1 2-(2'-methoxy)phenyl-1-vinylcyclohex-2-en-1-ol 
• 1027475-48-4 2-(2-Methoxy-phenyl)-3-(1-trimethylsilanyl-vinyl)-cyclohex-2-enol 
• 950585-03-2 (1S,2R)-2-(2-methoxyphenyl)-3-(dimethylphenylsilyl)cyclohexanone 
• 950584-78-8 (2R,3R)-2-(2-methoxyphenyl)-3-(dimethylphenylsilyl)cyclohexanone 
• 950584-77-7 (2S,3S)-2-(2-methoxyphenyl)-3-(dimethylphenylsilyl)cyclohexanone 

Relevant articles and documents

Asymmetric Hydrogenation of Racemic 6-Aryl 1,4-Dioxaspiro[4.5]decan-7-ones to Functionalized Chiral ?a'Aryl Cyclohexanols via a Dynamic Kinetic Resolution

A ruthenium-catalyzed asymmetric hydrogenation method for the synthesis of functionalized β-aryl cyclohexanols is described. With chiral spiro ruthenium catalyst (Ra,S,S)-5c, a series of racemic α-aryl cyclohexanones bearing a β-monoethylene ketal group were hydrogenated to the corresponding functionalized β-aryl cyclohexanols in high yields with enantioselectivity of up to 99% ee via a dynamic kinetic resolution. This protocol can be conducted on a decagram scale and provide potential approaches for the synthesis of optically active and densely functionalized aryl cyclohexanols.

The search for tolerant Lewis acid catalysts. Part 2: Enantiopure cycloalkyldialkylsilyl triflimide catalysts

A series of 2-aryl- and arylmethyl-3-dialkylphenylsilyl cycloalkanones have been prepared and resolved. The pure enantiomers were reduced to the corresponding cycloalkane derivatives. These were used for the in situ generation of enantiopure cycloalkylsil

Use of conjugated dienones in cyclialkylations: Total syntheses of arucadiol, 1,2-didehydromiltirone, (±)-hinokione, (±)-nimbidiol, sageone, and miltirone

Functionalized hydrophenanthrenes can be prepared using a cyclialkylation-based strategy. These annulations are highly dependent on the directing effects of the arene substitutents and on conformational considerations. The utility of this methodology was featured in the syntheses of six diterpenoids.