1372767-97-9Relevant academic research and scientific papers
Hybrid metal/organo relay catalysis enables enynes to be latent dienes for asymmetric diels-alder reaction
Han, Zhi-Yong,Chen, Dian-Feng,Wang, Ya-Yi,Guo, Rui,Wang, Pu-Sheng,Wang, Chao,Gong, Liu-Zhu
, p. 6532 - 6535 (2012/06/15)
The hybrid Au(I)/Bronsted acid binary catalyst system enables enynes to serve as latent 1,3-silyloxydienes capable of participating in the first cascade hydrosiloxylation of an enynyl silanol/asymmetric Diels-Alder reaction. A variety of polycyclic compounds bearing multistereogenic centers were obtained in high yields and excellent enantioselectivities from the relay catalytic cascade reaction between (2-(but-3-en-1-ynyl)phenyl) silanols and quinones catalyzed by the combined achiral gold complex and chiral N-triflyl phosphoramide.
