1372807-15-2Relevant academic research and scientific papers
Enantioselective Intramolecular Allylic Substitution via Synergistic Palladium/Chiral Phosphoric Acid Catalysis: Insight into Stereoinduction through Statistical Modeling
Chen, Buyun,Sandford, Christopher,Sigman, Matthew S.,Toste, F. Dean,Tsai, Cheng-Che,Wu, Tao
supporting information, p. 14647 - 14655 (2020/07/04)
The mode of asymmetric induction in an enantioselective intramolecular allylic substitution reaction catalyzed by a combination of palladium and a chiral phosphoric acid was investigated by a combined experimental and statistical modeling approach. Experi
Asymmetric intramolecular hydroamination of allenes using mononuclear gold catalysts
Michon, Christophe,Medina, Florian,Abadie, Marc-Antoine,Agbossou-Niedercorn, Francine
, p. 5589 - 5600 (2013/11/06)
The intramolecular gold-catalyzed asymmetric hydroamination of allenes was studied by screening a series of mononuclear gold(I) and -(III) complexes in combination with silver salts. Among the various chiral monophosphine and diaminocarbene ligands tried,
Silver-catalysed enantioselective addition of O-H and N-H bonds to allenes: A new model for stereoselectivity based on noncovalent interactions
Arbour, Jannine L.,Rzepa, Henry S.,Adrio, Luis A.,Barreiro, Elena M.,Hii, King Kuok,Contreras-Garcia, Julia
, p. 11317 - 11324,8 (2020/08/31)
The ability of silver complexes to catalyse the enantioselective addition of O-H and N-H bonds to allenes is demonstrated for the first time by using optically active anionic ligands that were derived from oxophosphorus(V) acids as the sources of chiralit
Gold(I)-catalyzed enantioselective intramolecular dehydrative amination of allylic alcohols with carbamates
Mukherjee, Paramita,Widenhoefer, Ross A.
, p. 1405 - 1407 (2012/03/11)
Aliphatic nitrogen heterocycles either five- or six-membered are formed in high yield and with up to 94 %ee when a 1:2 mixture of [(S)-2](AuCl)2 and AgClO4 is used as the catalyst for the title reaction. Copyright
