1372996-59-2Relevant academic research and scientific papers
An Upstream By-product from Ester Activation via NHC-Catalysis Catalyzes Downstream Sulfonyl Migration Reaction
Han, Runfeng,He, Liwenze,Liu, Lin,Xie, Xingang,She, Xuegong
supporting information, p. 193 - 197 (2016/03/01)
A sequential reaction combining N-heterocyclic carbene (NHC) and N-hydroxyphthalimide (NHPI) catalysis allowed for the upstream by-product NHPI, which was generated in the NHC-catalyzed cycloaddition reaction, to act as the catalyst for a downstream nitro
Enantioselective activation of stable carboxylate esters as enolate equivalents via N-heterocyclic carbene catalysts
Hao, Lin,Du, Yu,Lv, Hui,Chen, Xingkuan,Jiang, Huishen,Shao, Yaling,Chi, Yonggui Robin
, p. 2154 - 2157 (2012/07/14)
The first N-Heterocyclic Carbene (NHC) mediated activation of stable carboxylate esters to generate enolate intermediates is disclosed. The catalytically generated arylacetic ester enolates undergo enantioselective reactions with α,β-unsaturated imines.
