137303-41-4Relevant academic research and scientific papers
SYNTHESIS AND REGIOSELECTIVITY OF THE -SIGMATROPIC REARRANGEMENT OF SUBSTITUTED 2-ALLYLTHIO- AND 2-ALLYLSELENO-1,4-DIHYDROPYRIDINES
Litvinov, V. P.,Sharanin, Yu. A.,Goncharenko, M. P.,Dyachenko, V. D.,Shestopalov, A. M.
, p. 1675 - 1681 (2007/10/02)
The reaction of 3-cyano-1,4-dihydropyridine-2-thiolates and the corresponding selenolates with allyl bromide gave 2-allylthio- and 2-allylseleno-3-cyano-1,4-dihydropyridines, which, upon heating in various solvents or in the solid state, undergo -sig
UNUSUAL THERMAL SOLID-PHASE REARRANGEMENT OF 2-ALLYLTHIO- AND 2-ALLYLSELENODIHYDROPYRIDINES
Nesterov, V. N.,Shklover, V. E.,Struchkov, Yu. T.,Sharanin, Yu. A.,Goncharenko, M. P.,Dyachenko, V. D.
, p. 453 - 454 (2007/10/02)
A previously unreported thermal solid-phase migration of the allyl group was found for 2-allylthio- and 2-allylselenodihydropyridines, leading to 3-allyl-3-cyano-3,4-dihydropyridine-2(1H)-thiones and -selenones.Analysis of the crystal structures did not i
