1373128-08-5Relevant academic research and scientific papers
Intramolecular heterocyclization and cyclopalladation of selenoanisole substituted propargyl imines: Synthesis and reactivity of Pd-C bond towards alkynes
Racharlawar, Shailesh S.,Shankar,Karkhelikar, Manjusha V.,Sridhar,Likhar, Pravin R.
, p. 14 - 20 (2014)
The intramolecular cyclization of o-SeMeC6H4CCC- (CF3)(NAr) with [PdCl2(PhCN)2] to dimeric cyclopalladated benzoselenophene has been developed under mild conditions. The reactivity of the new dimeric
Heck-type coupling of intramolecularly-generated thiopalladacycles with alkenes: One pot syntheses of 3-alkenylbenzo[b]thiophenes
Karkhelikar, Manjusha V.,Racharlawar, Shailesh S.,Salian, Subhas M.,Sridhar,Likhar, Pravin R.
experimental part, p. 128 - 134 (2012/06/18)
A method for stoichiometric functionalization of benzothiophene is developed by Heck-type coupling of alkenes with intramolecularly-generated thiopalladacycles obtained from palladium salts and ortho-thioanisole- substituted propargyl imines. The syntheti
