1373264-69-7Relevant articles and documents
Strong electronic and counterion effects on geminal digold formation and reactivity as revealed by gold(I)-aryl model complexes
Weber, Dieter,Jones, T. David,Adduci, Laura L.,Gagne, Michel R.
, p. 2452 - 2456 (2012/04/17)
Geminal diauration of [Ph3PAu(aryl)] complexes has been investigated to model the intermediacy of geminally diaurated gold(I)-vinyl complexes in catalysis (see scheme). The results advance our understanding of the factors influencing the stability, reactivity, and dynamics of these organometallic intermediates. Copyright