137328-86-0Relevant academic research and scientific papers
Group- and electron-transfer reactions of tetracarbonylferrate(2-)
Zhen, Yueqian,Atwood, Jim D.
, p. 2778 - 2780 (2008/10/08)
Reactions of Fe(CO)42- with metal carbonyl complexes lead to distinct mechanisms. Reaction with metal carbonyl cations gives a two-electron process that we interpret as a CO2+ transfer. Reaction with Mn2(CO)10 occurs by a single-electron transfer producing Fe2(CO)82- and Mn(CO)5-. Reaction with Mn(CO)5Br also occurs by a single-electron transfer. Reaction with Re(CO)5Br could be either SET or direct nucleophilic displacement. Kinetic studies are reported for several reactions.
