1373344-91-2

Upstream product

• 1373344-90-1 1-phenyl-5-[[(3S)-3-[(trityloxy)methyl]pent-4-en-1-yl]thio]-1H-tetrazole 
• 1373344-89-8 (3S)-3-[(trityloxy)methyl]pent-4-en-1-ol 
• 943902-73-6 (+)-(S)-methyl 3-[(trityloxy)methyl]pent-4-enoate 

Downstream Products

• 1373344-94-5 methyl (2E,6R,8E,10E)-6-[[(triphenylmethyl)oxy]methyl]-dodeca-2,8,10-trienoate 
• 1373344-93-4 trityl (2S,4Z,6E)-2-vinylocta-4,6-dien-1-yl ether 
• 1373344-92-3 trityl (2S,4E,6E)-2-vinylocta-4,6-dien-1-yl ether 

Relevant academic research and scientific papers

Enantioselective total synthesis and absolute configuration of apiosporic acid

The first total synthesis of the polyketide apiosporic acid is presented. Key steps are a Julia-Kocienski olefination, a Suzuki-Miyaura cross-coupling, and an intramolecular Diels-Alder reaction. The absolute configuration of the natural product was determined.