13734-97-9

Upstream product

• 4941-84-8 4,6-dimethyl-[1,2]oxathiine 2,2-dioxide 
• 62-53-3 aniline 
• 93842-77-4 2,4-dimethylthiophene 1,1-dioxide 

Downstream Products

• 63650-79-3 5-hydroxy-3,5-dimethyl-1,1-dioxo-2-phenyl-2,5-dihydro-1H-1λ⁶-[1,2]thiazin-6-one 
• 94494-28-7 3,5-Dimethyl-1,1-dioxo-2-phenyl-1,2-dihydro-1λ⁶-[1,2]thiazine-6-carbaldehyde 
• 158468-22-5 6-(hydroxyiminomethyl)-4-methyl-1-phenylpyridazinium-3-sulfonate 
• 102118-47-8 2,3-Dicyano-4-[5-methyl-1,1-dioxo-2-phenyl-1,6-dihydro-2H-1λ⁶-[1,2]thiazin-(3E)-ylidene]-but-2-enenitrile 
• 93473-45-1 N-Phenyl-3-brom-4-brommethyl-1-chlor-2-methyl-buta-1,3-dien-1,4-sultam 
• 136435-58-0 1,1-Dioxo-3,5-di-(2',2'-dioxo-2'-thiapropyl)-2-phenyl-1,2-thiazine 
• 136435-54-6 3,5-Diiodomethyl-1,1-dioxo-2-phenyl-1,2-thiazine 
• 136435-51-3 3,5-Dichloromethyl-1,1-dioxo-2-phenyl-1,2-thiazine 
• 100033-32-7 1,3-Diiod-2,4-dimethyl-N-phenyl-buta-1,3-dien-1,4-sultam 
• 100033-30-5 2,4-Dimethyl-1-iod-N-phenyl-buta-1,3-dien-1,4-sultam 
• 93470-08-7 4-Chlormethyl-2-methyl-N-phenyl-4-(n-propyloxy)-1,1,3-trichlor-but-2-en-1,4-sultam 
• 93470-07-6 4-Chlormethyl-4-ethoxy-2-methyl-N-phenyl-1,1,3-trichlor-but-2-en-1,4-sultam 
• 87112-27-4 N-Phenyl-1.1.3-trichlor-2-methyl-4-methoxy-4-chlormethyl-buta-2-en-sultam-1.4 

Relevant academic research and scientific papers

Nitrosation of 2-Aryl-3,5-dimethyl-1,1-dioxo-1,2-thiazines - an Unusual Ringtransformation to Mesoionic Pyridazinium Salts

The thiazines 1b-e, g, h react with isoamyl nitrite/HClg by nitrosation of the 3-methyl group to the 3-cyano-thiazines 3b-e, g, h.As by-products the mesoionic pyridazinium salts 4b, c are formed.The compounds 4b-i and 4-1e-i became main products by nitros

Structure Elucidation of Bromination Products of N-Aryl-2,4-dimethyl-buta-1,3-diene-sultames-1,4

The structure of bromination products of N-aryl-2,4-dimethyl-buta-1,3-diene-sultames-1,4 1a-d, f is determined by 13-C-n.m.r. spectroscopy.As mono bromination product of N-phenylsultam 1a the 4-bromomethyl derivative 2a was isolated.Dibromination of sultames 1 yields 1-brom-4-brommethyl-sultames 3 and by tribromination 1,3-dibrom-4-brommethyl-sultames 4 are obtained.