1373431-99-2Relevant academic research and scientific papers
Thioboration of α,β-unsaturated ketones and aldehydes toward the synthesis of β-sulfido carbonyl compounds
Civit, Marc G.,Sanz, Xavier,Vogels, Christopher M.,Webb, Jonathan D.,Geier, Stephen J.,Decken, Andreas,Bo, Carles,Westcott, Stephen A.,Fernández, Elena
supporting information, p. 2148 - 2154 (2015/05/19)
Herein a direct β-sulfido carbonyl compound synthesis by the easy activation of RS-Bpin reagents with α,β-unsaturated ketones and aldehydes is reported. This convenient methodology can be performed at room temperature with no other additives. The key poin
Conjugate addition of unactivated thiols to α,β-unsaturated ketones catalyzed by a bifunctional rhenium(V)-oxo complex
Peng, Allan,Rosenblatt, Ross,Nolin, Kristine
supporting information; experimental part, p. 2712 - 2714 (2012/07/14)
ReOCl3(OPPh3)(S(CH3)2) has been found to be an efficient bifunctional catalyst for the 1,4-addition of thiols to α,β-unsaturated ketones. The addition of thiophenol derivatives and alkyl thiols proceeds under mi
