1373557-06-2

Basic information

• Product Name: (E)-1,2-bis(4-bromo-2-iodophenyl)diazene
• Synonyms: (E)-1,2-bis(4-bromo-2-iodophenyl)diazene
• CAS NO: 1373557-06-2
• Molecular Weight: 591.81
• Mol File: 1373557-06-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1,2-bis(4-bromo-2-iodophenyl)diazene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1,2-bis(4-bromo-2-iodophenyl)diazene(1373557-06-2)
• EPA Substance Registry System: (E)-1,2-bis(4-bromo-2-iodophenyl)diazene(1373557-06-2)

Safety Data

• Hazardous Substances Data: 1373557-06-2(Hazardous Substances Data)

Upstream product

• 1601-98-5 (E)-bis(4-bromophenyl)diazene 

Downstream Products

• 1373557-08-4 C₃₆H₆B₂Br₂F₂₀N₂ 

Relevant articles and documents

Rh(iii)-Catalyzed regioselective mono- and di-iodination of azobenzenes using alkyl iodide

A new approach for highly regioselective iodination of azobenzenes with alkyl iodide as the iodinating reagent enabled by Rh-catalyzed oxidative C-H activation has been developed. By changing the oxidant, various mono- and di-iodinated azobenzenes were smoothly obtained in moderate to excellent yields, respectively. The preliminary mechanistic study reveals that the reaction process might undergo electrophilic substitution of the directed ortho metalated five-membered rhodacycle compound by an iodine cationic species generated in situ from alkyl iodide and oxidant.