137364-32-0Relevant articles and documents
Controlled Synthesis and Molecular Structures of Methoxy-, Amino-, and Chloro-Functionalized Disiloxane Building Blocks
Espinosa-Jalapa, Noel Angel,Bauer, Jonathan O.
, p. 828 - 834 (2020)
Functionalized disiloxane units with defined structures are interesting molecular models for investigating the reactivity and chemoselectivity in transformations that are of interest in synthesis, surface chemistry, and materials science. (Mes)PhSi(OMe)s
Synthesis of Silacyclohexanones from Divinylsilanes and Allylamines by a Rh-Catalyzed Cyclization
Guo, Jiawei,Liu, Song,Pang, Qinjiao,Zhang, Hongyun,Gao, Lu,Chen, Li,Song, Zhenlei
supporting information, p. 726 - 730 (2022/01/20)
An efficient synthesis of silacyclohexanones bearing a variety of silyl substituents has been developed by a [Rh(coe)2Cl]2/PCy3-catalyzed cyclization of divinylsilanes with Jun’s allylamine. The silacyclohexanones can be o