137364-40-0Relevant academic research and scientific papers
ELECTRONIC EFFECTS AND MECHANISTIC FEATURES IN THE REARRANGEMENT-DISPLACEMENT REACTIONS OF ARYL(CHLOROMETHYL)DIPHENYLSILANES WITH FLUORIDE ION
Aprahamian, Steve L.,Shechter, Harold
, p. 1089 - 1092 (2007/10/02)
At 25 deg C aryl migrations from negatively-charged pentacoordinate silicon correlate with the abilities of the rearranging groups to bear negative charge, but at lower temperatures the migrations become less dependent on electron-withdrawing stabilization.
