137365-67-4Relevant academic research and scientific papers
Synthesis and characterization of [(Cp*)Ru(PPh3)(N-base)]X and [(η5-C9H7)Ru(PPh3)(N-base)]X complexes (see abstract)
Rao, Kollipara Mohan,Rymmai, Evergreen K.
, p. 307 - 312 (2008/10/08)
The reactions of [(η5-Cp*)Ru(PPh3)2 (CH3CN)]X (1) and [(η5-indenyl)Ru(PPh3)2 (CH3CN)]X (2) (η5-Cp* = η5-C5Me5; η5- indenyl = η5-C9H7; X = BF4 or PF6) with 2,2′-bipyridine (bipy.) and 1,10-phenanthroline (phen.) in benzene or toluene yielded complexes of the type [(η5-Cp*)Ru(PPh3)(L2)]X where L2 = bipy, X=BF4 (3) and L2=phen, X=PF6 (4); [(η5-indenyl)Ru(PPh3)2(L2)]X where L2 = bipy, X = PF6 (5) and L2 = phen, X = PF6 (6). Complex 6 has been established by single crystal X-ray diffraction analysis. Complex 6 crystallizes in the monoclinic space group P 21/c, with a = 14.6020 (12), b = 12.7100 (17) and c = 18.981 (2) A?, β = 98.982 (9)°, V = 3479.5 (7) A?3 and Z = 4. These complexes can also be prepared from reactions of [(η5- Cp*)Ru(PPh3)2Cl] (7) and [(η5-indenyl)Ru(PPh3)2Cl] (8) with the corresponding ligands in the presence of NH4PF6 or NH4BF4 in toluene. All the complexes were characterized by spectral and analytical data.
Preparation of electron-rich cationic complexes of the type [(η5-C5Me5)Ru(bipyridine)L]+
Balavoine, Gilbert G. A.,Boyer, Thierry,Livage, Carine
, p. 456 - 459 (2008/10/08)
Reaction of Cp*Ru(bpy)Cl (Cp* = C5Me5, bpy = 2,2′-bipyridine) with various monodentate two-electron donor ligands (L) in the presence of NH4PF6 gives [Cp*Ru(bpy)L]+PF6- (L = EtO
