1373759-05-7 Usage
Uses
Used in Metal Organic Frameworks (MOFs) Preparation:
4,4′-(2,2′-bipyridine-5,5′-diyl)dibenzoic acid is used as a key intermediate for the synthesis of Metal Organic Frameworks (MOFs). Its ability to form coordination bonds with metal ions, such as platinum (Pt), cobalt-bipyridine, and cobalt-phenanthroline, makes it an essential component in the preparation of these advanced porous materials.
MOFs are a class of materials with unique properties, including high surface area, tunable pore size, and adjustable chemical functionality. They have a wide range of applications, including gas storage, separation, catalysis, and drug delivery, due to their structural diversity and design flexibility.
In the Chemical Industry:
4,4′-(2,2′-bipyridine-5,5′-diyl)dibenzoic acid is used as a building block for the development of new coordination complexes and supramolecular assemblies. Its bipyridine core and benzoic acid groups enable the formation of various coordination geometries, which can be exploited to create novel materials with tailored properties for specific applications.
In the Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, the structural similarity of 4,4′-(2,2′-bipyridine-5,5′-diyl)dibenzoic acid to certain ligands used in medicinal chemistry suggests that it may have potential applications in the design of new drugs, particularly those targeting metalloenzymes or requiring coordination to metal ions for biological activity.
In the Materials Science Field:
4,4′-(2,2′-bipyridine-5,5′-diyl)dibenzoic acid can be used as a component in the development of new materials with specific optical, electronic, or magnetic properties. The coordination chemistry of the bipyridine motif and the potential for functionalization of the benzoic acid groups allow for the fine-tuning of these properties, making it a valuable asset in the creation of advanced materials for various applications, such as sensors, catalysts, or energy storage devices.
Check Digit Verification of cas no
The CAS Registry Mumber 1373759-05-7 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,7,3,7,5 and 9 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1373759-05:
(9*1)+(8*3)+(7*7)+(6*3)+(5*7)+(4*5)+(3*9)+(2*0)+(1*5)=187
187 % 10 = 7
So 1373759-05-7 is a valid CAS Registry Number.
1373759-05-7Relevant academic research and scientific papers
Huang, Ruiyun,Peng, Yu,Wang, Cheng,Shi, Zhan,Lin, Wenbin
, p. 4358 - 4362 (2016)
A metal–organic framework (MOF) based on (bpy)Re(CO)3Cl-containing elongated dicarboxylate ligands and Zr6(μ3-O)4(μ3-OH)4clusters was synthesized and used as an effective single-site catalyst to photochemically reduce carbon dioxide to carbon monoxide and formate and to provide mechanistic insights into the photocatalytic CO2reduction process.
Merging Photoredox and Organometallic Catalysts in a Metal–Organic Framework Significantly Boosts Photocatalytic Activities
Zhu, Yuan-Yuan,Lan, Guangxu,Fan, Yingjie,Veroneau, Samuel S.,Song, Yang,Micheroni, Daniel,Lin, Wenbin
, p. 14090 - 14094 (2018/10/15)
Metal–organic frameworks (MOFs) have been extensively used for single-site catalysis and light harvesting, but their application in multicomponent photocatalysis is unexplored. We report here the successful incorporation of an IrIII photoredox catalyst and a NiII cross-coupling catalyst into a stable Zr12 MOF, Zr12-Ir-Ni, to efficiently catalyze C?S bond formation between various aryl iodides and thiols. The proximity of the IrIII and NiII catalytic components to each other (ca. 0.6 nm) in Zr12-Ir-Ni greatly facilitates electron and thiol radical transfers from Ir to Ni centers to reach a turnover number of 38 500, an order of magnitude higher than that of its homogeneous counterpart. This work highlights the opportunity in merging photoredox and organometallic catalysts in MOFs to effect challenging organic transformations.
