137376-38-6Relevant articles and documents
Functionalised mesoporous silica: A good opportunity for controlled peptide oligomerisation
Subra, Gilles,Mehdi, Ahmad,Enjalbal, Christine,Amblard, Muriel,Brunel, Luc,Corriu, Robert,Martinez, Jean
, p. 6321 - 6326 (2011)
In this paper, mesoporous organosilicas functionalised with aminopropyl groups have been successfully used for peptide oligomerisation. For this purpose, three mesoporous silica SBA-15 type containing different amounts of aminopropyl groups were prepared
A reliable method to create adjacent acid-base pair sites on silica through hydrolysis of pre-anchored amide
Kim, Wontae,Casalme, Loida O.,Umezawa, Taiki,Matsuda, Fuyuhiko,Otomo, Ryoichi,Kamiya, Yuichi
, p. 71 - 74 (2020)
A method to create adjacent acid-base pair sites, which are carboxyl and amino groups, respectively, on silica through hydrolysis of pre-anchored amide is proposed. This method can produce an adjacent acid-base pair site. The catalyst showed excellent catalytic performance for aldol condensation of 4-nitrobenzaldehyde with acetone, overwhelming the catalyst having only amino group and an acid-base catalyst prepared in a conventional manner.
A yolk-shell nanoreactor with a basic core and an acidic shell for cascade reactions
Yang, Yan,Liu, Xiao,Li, Xiaobo,Zhao, Jiao,Bai, Shiyang,Liu, Jian,Yang, Qihua
supporting information, p. 9164 - 9168 (2012/11/07)
Smart yolk-shell nanoparticles (hollow nanoparticles with a movable core) with an acidic shell and a basic core were fabricated through an organosilane-assisted selective etching method and acted as efficient nanoreactors for catalyzing a deacetalization-Henry cascade reaction with high activity and high selectivity. This strategy is very promising for the design of multifunctional nanoreactors for cascade reactions. Copyright