1373776-08-9

Basic information

• Product Name: C₃₈H₄₀NOPS₂
• CAS NO: 1373776-08-9
• Molecular Weight: 621.847
• Mol File: 1373776-08-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₈H₄₀NOPS₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₈H₄₀NOPS₂(1373776-08-9)
• EPA Substance Registry System: C₃₈H₄₀NOPS₂(1373776-08-9)

Safety Data

• Hazardous Substances Data: 1373776-08-9(Hazardous Substances Data)

Upstream product

• 1202567-68-7 9-dodecyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole 
• 1240575-39-6 2-bromodithieno[3,2-b:2',3'-d]phosphole oxide 

Relevant articles and documents

Synthesis and unexpected halochromism of carbazole-functionalized dithienophospholes

A series of π-conjugated donor-acceptor (D/A) chromophores using dithieno[3,2-b:2′,3′-d]phosphole oxide as an acceptor and 3,6-carbazole as a donor component have been synthesized and characterized. The studies involved several molecular species with D-A, A-D-A, D-A-D architecture, as well as a polymeric species (D-A)n. The different photophysical properties of the systems can be attributed to the carbazole unit de facto acting as aniline species for the π-conjugated system. Treatment of the donor-acceptor materials with acids resulted in the significant red shift of the absorption and emission wavelengths and the process was found to be reversible. Investigations via Density-Functional Theory (DFT) calculations revealed the nature of the unexpected red shift upon protonation. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2012.