137384-87-3

Upstream product

• 137384-85-1 (3aR,4R,5S,7S,7aS)-4-Allyl-5-benzenesulfonyl-5-bromo-2,2,3a,7-tetramethyl-hexahydro-benzo[1,3]dioxole 
• 137384-84-0 (3aR,4R,7S,7aS)-4-Allyl-5-benzenesulfonyl-2,2,3a,7-tetramethyl-hexahydro-benzo[1,3]dioxole 

Downstream Products

• 137393-08-9 ((3aR,4R,5R,7S,7aS)-5-Benzenesulfonyl-5-cyclohexanecarbonyl-2,2,3a,7-tetramethyl-hexahydro-benzo[1,3]dioxol-4-yl)-acetic acid methyl ester 
• 137384-92-0 ((3aR,4R,5R,7S,7aS)-5-Benzenesulfonyl-5-cyclohexanecarbonyl-2,2,3a,7-tetramethyl-hexahydro-benzo[1,3]dioxol-4-yl)-acetic acid 
• 137384-93-1 (2aR,4S,4aS,7aR,7bR)-2a-Benzenesulfonyl-4,6,6,7a-tetramethyl-hexahydro-5,7-dioxa-cyclobuta[e]inden-2-one 
• 137384-88-4 C₂₆H₃₅BrO₇S 

Relevant academic research and scientific papers

Intramolecular Acylation of an α-Sulfonyl Anion Generated via Halogen-metal Exchange of an α-Halosulfone Bearing an Unsymmetrical Anhydride

α-Halosulfones are useful for the in situ preparation of α-sulfonyl anions in the presence of acylating agents bearing enolizable protons.Inter- and intramolecular acylations can be effected by halogen-metal exchange at low temperature.